Roger Federer will be bidding to increase his tournament leading total, while Djokovic is keen to win the only Masters 1000 tournament missing from his trophy collection.
The seven-time champion beat fellow Swiss Stan Wawrinka 6-7 (2/7), 7-6 (8/6), 6-2.
Novak Djokovic is aiming to lift the trophy at the only one of the Masters 1000 series events that he has never won.
Novak Djokovic is vying to break through for a first Cincinnati Masters win after coming up empty in five finals.
Leander Paes was already miffed at his exclusion from TOP Scheme.
Leander Paes did not travel to Indonesia with the rest of the squad.
Novak Djokovic called for the doctor during the second set against Adrian Mannarino but put aside his discomfort to progress 4-6, 6-2, 6-1.
Sania Mirza and her cricketer husband Shoaib Malik got married in 2010.
Former US Open champions Stan Wawrinka and Svetlana Kuznetsova received wildcards into the event on Tuesday along with two-time Australian Open winner Victoria Azarenka, tournament organisers announced.
Roger Federer began his US Open preparation with a comprehensive 6-4, 6-4 defeat of Peter Gojowczyk in a first ATP Cincinnati Masters appearance since 2015.
Serena Williams re-established her customary superiority, hammering Daria Gavrilova 6-1, 6-2 to reach the second round of the Cincinnati Masters on Monday.
Roger Federer on Monday said he is eager to make his start at the Cincinnati Masters as the world number two begins his delayed summer hardcourt season.
Rafael Nadal withdrew from next week's ATP Cincinnati Masters event as he prepares for the US Open.
The 32-year-old scooped the 80th title of his career earlier Sunday with victory at the Toronto Masters.
In a gruelling 2hr 41min battle, French Open champion Halep prevailed 7-6 (8/6), 3-6, 6-4 over Stephens in a repeat of the duo's meeting in the final of Roland Garros earlier this year.
The win gave the 32-year-old Spaniard a record-extending 33rd trophy at the elite Masters level as well as his 80th title.
Rafael Nadal beat Karen Khachanov 7-6 (7/3), 6-4 on Saturday to set up a final with birthday boy Stefano Tsitsipas at the Toronto Masters.
American third seed Stephens surged into Sunday's final against world number one Halep after overpowering Svitolina 6-3, 6-3 in the day's second semi-final.