Luis Rubiales kissed Spanish footballer Jenni Hermoso after the team's historic victory over England in FIFA Women's World Cup final and that led to a massive controversy.
Jenni Hermoso and 80 other Spain players, including the entire World Cup squad, said they will not play for the national team until the Spanish football federation (RFEF) "leadership" changes.
Spanish football federation president Rubiales has been widely criticised for kissing player Jenni Hermoso on the lips as the Spanish team celebrated winning the Women's World Cup in Sydney last Sunday.
Jenni Hermoso, along with 80 other Spain players, including the entire World Cup winning squad, said they were striking from the national team until the "leadership" changed.
In a statement released by women players' union Futpro, Jenny Hermoso and 80 other players said they would not accept an international call-up "if the current leadership continues" in Spanish FA.
Rubiales, 46, will submit his resignation as president of the Spanish football federation (RFEF) on Friday at an extraordinary general assembly, according to the reports.
Luis Rubiales was criticised on social media for his celebration with Jenni Hermoso during the medal ceremony after Spain beat England 1-0 to win the FIFA Women's World Cup.
Spain's goalscoring hero Olga Carmona hailed her "unstoppable" side as they beat England 1-0 to win the Women's World Cup for the first time on Sunday in Sydney