Scott McTominay scored an injury-time winner as Scotland beat Israel in World Cup qualifying, while England thrashed Andorra 5-0 to stay on track to reach next year's global showpiece.
Mason Mount and Ben Chilwell embraced Scotland midfielder Billy Gilmour, their team-mate at Chelsea, on the Wembley pitch after England's 0-0 draw with Scotland on Friday.
Euro 2020: Scotland midfielder Billy Gilmour tested positive for COVID-19 and he will miss Tuesday's match against Croatia at Hampden.
UEFA EURO 2020: Czech Republic's Patrick Schick scored an outrageous halfway line goal to double the lead against Scotland.
Scotland can look forward to a trip to Wembley to play England, and will also face the Czech Republic and Croatia in Glasgow in Group D at the Euro 2020 finals.
Czech coach Jaroslav Silhavy will be absent from the team's match against Scotland in the Nations League as he has tested positive for COVID-19.
Scotland are one game away from reaching the UEFA Euro 2020 and also their first major tournament in 22 years.
According to UEFA's new regulations for international fixtures which were announced last week, matches will go ahead as long as a team has 13 available players after Covid-19 testing.
Scott McTominay has made 28 appearances for Manchester United in all competitions this season, and has been one of manager Ole Gunnar Solskjaer's standout players.
Kevin De Bruyne set up three goals inside the first 32 minutes before capping a brilliant individual display by rounding off the scoring.
The Kazakhs, ranked 117th in the world, struck twice inside 10 minutes through Yuriy Pertsukh and Yan Vorogovskiy.
Belgium showed their class and no hangover from their exertions in finishing third in Russia to warm-up for their Nations League opener against Iceland.
Scotland's sole victory over Italy came in 1965 and this was the sides' first meeting since a Euro 2008 qualifier