Real Madrid and Manchester City will face off in a Champions League knockout tie for the fifth season running.
Vinicius scored the winning goal in a 2-1 victory on the night to secure a 3-1 aggregate success for Real in the play-off tie in Madrid.
UEFA suspended midfielder Gialuca Prestianni from Benfica's Champions League play-off second leg against Real Madrid this week after he was accused of racially abusing Vinicius Junior.
Vinicius Junior is set to face Gianluca Prestianni again in the Champions League, just a week after accusing the Benfica player of racially insulting him.
Vinicius Junior was back on the score sheet for Real Madrid on Saturday, but the Brazilian was not able to prevent the Spanish league leader from falling to a surprise 2-1 loss to Osasuna.
Madrid defender Trent Alexander-Arnold called the incident "a disgrace to football" while Benfica manager Jose Mourinho said Vincius had incited his players and fans by the way he celebrated his goal in the 1-0 win for Madrid.
Vinicius Junior scored and then alleged he had been racially abused during Real Madrid's 1-0 win away to Benfica in the first leg of their Champions League play-off tie on Tuesday, while Paris Saint-Germain came from two goals down to beat Monaco 3-2.
Real Madrid vs Benfica Live Streaming UEFA Champions League Live Telecast: When And Where To Watch
With Kylian Mbappe back in the squad, Real Madrid returns to Portugal looking for some payback against Jose Mourinho's Benfica in the Champions League.
Vinicius Junior won and converted two penalties as Real Madrid thumped Real Sociedad 4-1 on Saturday to move provisionally top of La Liga.
The European Super League saga drew towards an end as Real Madrid, the last club still involved in the failed breakaway project, and UEFA announced Wednesday they had come to an agreement which will help resolve their legal dispute.
Kylian Mbappe scored his 23rd goal of the season in La Liga to help Real Madrid claim a battling 2-0 win at Valencia on Sunday and close the gap to leaders Barcelona to one point.
Real Madrid vs Valencia Live Streaming La Liga Live Telecast: When And Where To Watch
Real Madrid coach Alvaro Arbeloa and his star striker Kylian Mbappe agree on at least one thing, ahead of Sunday's visit to face Valencia in La Liga -- the need for consistency.
Real Madrid midfielder Jude Bellingham is expected to miss the club's upcoming Champions League play-off matches against Benfica after suffering a hamstring injury on Sunday.
Kylian Mbappe stayed calm to roll home a 100th-minute penalty and claim Real Madrid a 2-1 win over nine-man Rayo Vallecano on Sunday in a spicy La Liga derby clash.
Real Madrid vs Rayo Vallecano LIVE Streaming, La Liga LIVE Telecast: When And Where To Watch
Real Madrid faces an immediate rematch with Benfica after the teams were drawn together in the Champions League playoffs on Friday.