Nani, who had seen a penalty saved in normal time before the game finished in a 1-1 draw, made no mistake in the shoot-out with his side's fifth and final spot-kick.
France have won their last 10 meetings with the Portuguese since going down 2-0 in a friendly in 1975. Their head-to-head record includes victories in all three clashes at major competitions
Cristiano Ronaldo scored a magnificent brace as Portugal drew with Hungary 3-3 to qualify for the round of 16 in an exciting Euro 2016 encounter
Nani spent all of last season on loan at his former club Sporting Lisbon and was not expected to figure in manager Louis van Gaal's plans for the coming season.
Nani joined Manchester United from Sporting Lisbon in 2007 and during his time at Old Trafford he has won four Premier League titles and a Champions League crown.
In his autobiography, Alex Ferguson said Liverpool captain Steven Gerrard "was not a top, top player" and questioned some of Kenny Dalglish's signings during his second spell as manager between 2011 and 2012.
Bosnia-Herzegovina -- who had lost to Portugal in play-offs for the 2010 World Cup and Euro 2012 -- reach their first ever major finals.
Earlier this week, Suarez accused Liverpool of breaking promises by preventing him from joining another club, but manager Brendan Rodgers has refuted that and forced the Uruguayan to train on his own.
The 32-year-old joined Manchester City in 2009, and was initially installed as captain. But he lost his place in the starting line-up and moves to Liverpool when his contract expires on July 1.
The game vs QPR brought down the curtain on the 35-year-old defender's illustrious career, and he was afforded a guard of honour from both sets of teams before being handed a memento from the opposition's Liverpool-born captain Clint Hill.
A 1-0 win for Arsenal over Newcastle sealed the final qualifying spot for the Champions League and forced Tottenham to settle for a Europa League place.
Carragher has spent his whole career at Anfield, winning the Champions League, two FA Cups and three League Cups, and the Merseyside-born star will fittingly bow out as captain for his 737th and last appearance for the Reds on Sunday against QPR.
Carragher made his Liverpool debut in January 1997 and was a member of the team that won three trophies - the FA Cup, League Cup and UEFA Cup - in 2001 and then the Champions league in 2005.
Portugal coach Paulo Bento is sweating over the fitness of three key players - Cristiano Ronaldo, defender Pepe and midfielder Raul Meireles - for Friday's World Cup qualifier against Russia in Moscow.
Portugal Winger Ricardo Quaresma and defender Miguel Lopes had a training ground bust-up, the Portuguese press reported on Saturday, days ahead of their semi-final appearance at Euro 2012.
The Czech Republic will look on Thursday to put a halt to Cristiano Ronaldo and his Portuguese side's growing momentum and book their place in the semi-finals of Euro 2012.
Portugal coach Paulo Bento turned his ire on critics of misfiring captain Cristiano Ronaldo on Saturday, the day before his side's crucial final Euro 2012 Group B match with the Netherlands.
Netherlands coach Bert van Marwijk admits his side have no option but to attack if they are to secure the two-goal win over Portugal on Sunday that they need to reach the Euro 2012 last eight.