The other quarter-final match-ups feature Dutch hope Richel Hogenkamp against Czech Republic third seed Klara Zakopalova while French veteran Virginie Razzano takes on Italy's Flavia Penneta.
Serena drubbed Anna Tatishvili 6-0, 6-1 in the first round. Serena hasn't won French Open title since 2002 and hasn't reached the semifinals since 2003.
World number one Caroline Wozniacki survived a second-set fightback from Georgia's Anna Tatishvili to reach the Australian Open's third round 6-1, 7-6 (7/4) on Wednesday.
Top-seeded Vera Zvonareva had to battle for over three hours to beat Georgia's Anna Tatishvili 7-5, 6-7 (4), 6-2 on Friday and reach the semifinals of the Baku Cup.
Former top-ranked Ana Ivanovic made a stomping start to her Wimbledon buildup with a victory in less than 45 minutes in the Aegon Classic on Wednesday.