Serial Champions League winners Real Madrid bared their fangs but left Munich staring down the barrel of a second consecutive season without a major trophy with coach Alvaro Arbeloa's tenure looking tenuous.

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The treble by Federico Valverde came after his last-gasp goal snatched Madrid a 2-1 win at Celta Vigo in the Spanish league's previous round.

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Federico Valverde's heavily deflected 95th-minute drive snatched injury-hit Real Madrid a 2-1 win at Celta Vigo in La Liga on Friday.

Vinicius Junior won and converted two penalties as Real Madrid thumped Real Sociedad 4-1 on Saturday to move provisionally top of La Liga.

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Alvaro Arbeloa's first match at the helm ended in humiliation, a 3-2 defeat by Albacete in the Copa del Rey last 16 on Wednesday.