This is also the fifth time that India have gone in without a specialist spinner.
Leading the four-Test series 1-0, India will play the second Test against Australia in Perth, starting Friday.
Ravindra Jadeja was the pick of the bowlers in the fifth ODI, picking four wickets for 34 runs.
MS Dhoni effected a stumping to dismiss Windies player Keemo Paul in only 0.08 seconds.
Rishabh Pant is in line to make his ODI debut with India announce the XII for the first match against the Windies on Sunday.
India won the Test matches in Rajkot and Hyderabad to seal the series 2-0 against the Windies.
The tourists were dismissed for 196 early in the final session while following on, to trail the two-match series 1-0.
India beat West Indies by an innings and 272 runs to go 1-0 up in the two-match Test series.
Ravindra Jadeja almost messed up an easy run-out with both batsmen stranded at the same end.
The incident took place during the 12th over when a bad call saw both Windies batsmen Sunil Ambris and Shimron Hetmyer at the same end.
India were in a commanding position with the West Indies struggling to deal with the home side.
The Windies were struggling at 94 for 6 in their first inning after India ended at 649 for 9 declared.
Ravindra Jadeja became India's third centurion of the ongoing Test match, after debutant Prithvi Shaw and Virat Kohli made the West Indian attack look helpless.
Ravindra Jadeja starred with both bat and ball in the Asia Cup final against Bangladesh.
Ravindra Jadeja claimed four wickets in the Super Four match against Bangladesh in the Asia Cup 2018.
Highlights India vs England: Alastair Cook stars with the bat on his farewell Test while England pacers James Anderson and Stuart Broad picked up early wickets to put India on the back-foot at end of Day4.
India were dismissed for 292 in reply to England's first-innings 332.
Ravindra Jadeja along with debutant Hanuma Vihari (56), stitched a crucial partnership for the seventh wicket.