Marcus Rashford returns to Paris Saint-Germain with Aston Villa on Wednesday seeking a hat-trick of wins at the home of the French champions
Aston Villa sit below fifth-placed Manchester City only on goal difference and moved to within one point of Chelsea in fourth.
Ian Maatsen scored in between Marco Asensio's brace as Unai Emery's side romped to a 6-1 aggregate victory.
Ousmane Dembele has never been a deadly finisher and was guilty of missing a couple of big chances in the first half.
Bradley Barcola scored twice while Marco Asensio, Achraf Hakimi, Warren Zaire-Emery and Lee Kang-in were also on target.
PSG are now 13 points clear at the top of the table, a gap that second-placed Brest can trim to 10 points by beating Metz on Sunday.
Kylian Mbappe was rested for PSG's Ligue 1 win over Lille at the weekend to make sure he was fully fit for Wednesday's clash against La Real at the Parc des Princes.
Real Madrid were made to wait, but eventually conjured a stylish 2-0 victory at Cadiz on Saturday in La Liga, ahead of their Champions League trip to face Chelsea
Real Madrid's hopes of retaining the La Liga title were dented Sunday as the champions lost 1-0 at Real Mallorca, to remain five points behind leaders Barcelona.
Marco Asensio opened the scoring for Real Madrid as they went on to beat Valencia 2-0 in La Liga.